Yes, you can connect it to your laptop, but it won't sync with iTunes. You will need to set the USB to File Transfers (it should ask when you connect it), then you can just transfer music files and folders direct from your PC to the SD card on the phone. So, you can transfer your iTunes library, but you'll need to copy the iTunes Music folder direct. If you have set iTunes to organise files and folders, all your albums should appear correctly on the phone.