As far as I know Dave you will have a TS folder on your hard drive or DVD that has the original VOB, BUP and IFO files in it which relate to that particular dvd.
You said previously that you wanted to create a compilation from various dvds you had made.
So if you open Nero Burning Rom and go to Create a DVD it will bring up the new compilation window on the left, it will have an Audio folder and a TS folder.
From what I have read, if you drag the selected VOB, BUP and IFO files from the original TS folder for each track that you want to add to your new compilation into the new compilation TS folder then that shuld do it.
I havent tried it myself but have read a lot about it from different sites and thats my understanding of it.
It also appears that the earlier versions of Nero Vision Express 2 do indeed re-encode the VOB files which slow the whole process down and I have heard can cause audio/video synchronisation problems.
I would use Vision Express 2 only if you needed to encode a dvd and not for doing what you are wanting to do